■体裁:B5判、118ページ
■発刊:2009/04
■ISBNコード: 978-4-7813-0106-8
■シーエムシー出版

2008年『色素増感太陽電池研究者のための色素データ集』　英文版

【著者】
Tamotsu Horiuchi　　 Specialist　Advanced Technology R&D Center　Research and Development Group　RICOH COMPANY,LTD.
Jun-ichi Fujisawa　　 Assistant Professor　Research Center for Advanced Science and Technology　The University of Tokyo
Satoshi Uchida　　　 Associate Professor　Research Center for Advanced Science and Technology　The University of Tokyo
Michael Gratzel　　　 Professor Director,Laboratory of Photonics and Interfaces Ecole Polytechnique Federale de Lausanne


【序文】
本書は,2008年7月に発行された『色素増感太陽電池研究者のための色素データ集』の英語翻訳版となっております。
　同時に,毎日のように新しい色素が発表される色素増感太陽電池業界のめまぐるしい動きに合わせ,本書は改訂版としての役割も果たしています。
　前書は,これまでに発表されている色素増感太陽電池用色素67種類について,分子構造や光吸収特性に関わる基礎的物性をまとめましたが,今回は,前書の色素に加え,「ポルフィリン色素」をはじめとして,新たに約20もの色素を追加し,EPFLのグレッツェル先生の御協力も得て,先日効率12.3%を報告した新色素「Z991」も収録しました。



Book description(Preface)
　In light of the fight against global warming,the widespread use of natural energy can not be delayed any longer.
　In this backdrop,dye-sensitized solar cells have attracted considerable attention in all aspects as low-cost next-generation power-generating devices.This is the only type of solar cell which is capable of having colorful designs, transparency and flexibility.By taking advantage of these many features,even from the standpoint of photovoltaic devices,the time is not far off when the dye-sensitized solar cell becomes widespread and grows into an industry which can actively support future energy.In order to realize its practical application and to establish itself as an industry,further improvements towards higher conversion efficiency and better durability are necessary.Thus,constant development of new materials is essential.In particular, the refinement of dyes plays a crucial role in fulfilling this task.
　This book is a compilation of86 kinds of dyes used in dye-sensitized solar cells,which have been reported so far,including their molecular structures and fundamental physical properties.
　I received the full support of Dr.Fujisawa in data collection and also in the calculation and visualization of the HOMO and LUMO of the dyes.In addition to data gathering, Mr.Horiuchi,who stood at the frontier of this research field,traced the origin and trends of the various types of dyes.Beginning with a historical account of the earlier stages,he extensively lays out the development of the organic dyes until they reach their most recent transformation with significantly enhanced performance.
　From hereon,it is my deepest wish to further expand this dye database.I fervently hope that this book can someday contribute to the research advancement of dye-sensitized solar cells.
　Finally,I would like to take this opportunity to thank everyone who has provided data for the publication of this book and Dr.Joanne T.Dy for her help in editing this manuscript.

April,2009
Representative of the authors　　Satoshi Uchida

【目次】
【PART　Research Trend of Dye-Sensitized Solar Cells】
1.　Introduction
2.　Dye sensitizers
3.　Xanthene dyes
4.　Perylene dyes
5.　Dye sensitizers for silver-salt based photography
6.　Coumarin dyes
7.　Polyene dyes
8.　Porphyrin dyes
9.　Phthalocyanine dyes
10.　Polymer dyes
11.　Indoline dyes
12.　Thiadiazole
13.　Debelopment of the Ar moiety
14.　Extending the wavelength span of indoline dyes
15.　Properties of D149 and D150
16.　Electrochemical properties of dyes
17.　Comparison of CV data between D102 and D149
18.　TG-DTA data of dyes
19.　Summary of indoline dyes
20.　About D205
21.　Other metal oxides with indoline dyes
22.　Solid-state DSSC
23.　Summary

【PART2】
Anthocyanine
BBAPDC
C101
C102
Cyanine Dye (B1)
Cyanine Dye (C1-D)
Cyanine Dye (SQ-3)
CYC-B1
D5
D7
D9
D11
D77
D102
D120
D131
D149
D150
D190
D205
Eosin Y
H2TC1PP
H2TC4PP
HRS-1
ID28
ID34
JK-1
JK-2
K9
K19
K51
K60
K73
K77
Mercurochrome
MK-2
N3
N621
N712
N719
N749
N820
N823
N845
N886
N945
N ?
NKX-2311
NKX-2510
NKX-2569
NKX-2586
NKX-2587
NKX-2677
NKX-2697
NKX-2753
NKX-2883
NKX-?
Pendant type Polymer
Phthalocyanine Dye
Phthalocyanine Dye
Phthalocyanine Dye(TT-1)
Polythiophene Dye(P3TTA)
PPDCA
PTCA
SCN2Ru-Ni
TA-St-CA
WMC217
WMC234
WMC236
WMC239
WMC273
Z316
Z907
Z907Na
Z910
ZnTPP